Surface Analysis and Materials Characterization


An Introduction to Ellipsometry

Course Objectives
• Understand the physical phenomena involved in ellipsometry.
• Learn how the optical properties of materials and thin films are related to the ellipsometric parameters.
• Learn how to analyze ellipsometric spectra to determine material optical properties and film thickness.
• Learn how to relate optical constants to thin films and bulk material microstructure
• Learn how to use ellipsometry for the study and control of process kinetics.
• Learn the types of problems that can be solved with ellipsometry


Course Description

This course is an introduction to reflection spectroscopic ellipsometry that is a non-destructive and non-invasive optical technique for material/thin film analysis. Single-wavelength real time ellipsometry is also covered to introduce the attendant to the monitoring and study of process kinetics. This course emphasizes:
  • The principles of reflection elliposmetry – polarized light, light reflection, the concept of dielectric function, while including a minimum of mathematics.
• Qualitative analysis - identification of materials, surface roughness effects, oxidation effects, density effects.
• Quantitative analysis – effective medium approximation approaches to resolve microstructure, multi-layer systems, and nanostructured systems, the ability to measure the thickness of several layers simultaneously
• Applications to solve surface-related problems.
• Applications of real time ellipsometry to monitor, study and control growth and processing of thin films
• The class will discuss applications of the techniques in the areas of material growth and processing, microelectronics, optoelectronics, organic film, monolayers and others.


Who Should Attend?
Scientists, engineers, technicians, and others entering the field of the analysis of thin films and of the processing and growth of material/thin films.

Course Materials:
Course Notes
Suggested textbook: H.G. Tompkins, “A User’s Guide to Ellipsometry” Academic Press, Inc.

Instructor:
Maria Losurdo, Senior Scientist at IMIP-CNR, Bari, Italy

Short Curriculum
Dr. Maria Losurdo took the PhD in Material Science at Università di Bari, Italy. The research being performed by Dr. Maria Losurdo is directed in fundamental areas of plasmachemistry, as well as in applied areas of materials science. Thin-film preparation and the optical properties of solids are the two dominant themes in much of this research.
The fundamental research component involves understanding the interaction of plasmas with surfaces and optical properties of ultrathin films and clusters. It also involves characterizing and understanding the chemical processes that occur during thin-film nucleation and growth, as well as during treatments for surface modifications (cleaning, passivation, oxidation, nitridation,….). Reference materials are silicon and III-V semiconductors, metal oxides, high-K dielectrics, polymers.

The applied component of Dr. Losurdo's research involves studying the ability to control the nucleation and growth processes through certain experimentally controllable features (i.e., the chemical species that are the building blocks of the film, as well as the energy with which these species impact the substrate/film). The choice of complex technologically relevant systems in addition to model systems contributes to the challenge of the research. Much of Dr Losurdo's research involves the use of a monolayer-sensitive optical probe called spectroscopic ellipsometry that can be used in situ and in real time during the formation of clusters and thin films. Another critical component of Dr. Losurdo's research involves the modeling of optical properties of materials to stay in the forefront of research in the area of optical properties of solids and development of surface treatment/growth processes.
On the above topics, Dr. Losurdo has about 100 original publications in JCR journals and over 100 presentations at International Conferences.

Questions?: cscpml18@area.ba.cnr.it